Heat Treatment Featuring the Key-Parameters of High Chromium White Cast Iron Microstructure
DOI:
https://doi.org/10.30544/MMD12Abstract
The high chromium white cast iron (HCWCI) has been on the scene for decades, with expectations to remain there due to its exceptional wear resistance. HCWCI is mostly applied as-cast, but it can also be used as a coating material. The carbides in HCWCI microstructure, whose composition depends on alloying and heat treatment regime, give this special feature to white cast irons. The investigation presented in this paper was carried out by examining two HCWCI alloys, denoted HCWCI_1 and HCWCI_2, both alloyed with molybdenum in addition to high chromium content. The HCWCI_1 alloy contains 24.48% Cr with 1.32% Mo, and HCWCI_2 contains 14.11% Cr with 2.47% Mo. Comprehensive qualitative microstructural characterization was performed on all types of samples: as-cast samples, those obtained after quenching (at -196 °C) and/or quenching followed by tempering (at 250 °C). Besides standard etching procedures, the selective color etching was also applied here. The microstructure parameters, such as width of secondary dendritic arms and carbides size, are measured and correlated with applied alloy obtaining procedure and heat treatment regime, so they can be discussed in relation to the microconstituent’s ratio (such as ratio of different carbides) and morphology.
Keywords:
dendrite arm spacing, wearing, molybdenum, carbides, eutecticReferences
Agunsoye, Johnson O., Talabi S. Isaac, and Agbeleye A. Abiona. "On the comparison of microstructure characteristics and mechanical properties of high chromium white iron with the Hadfield austenitic manganese steel." Journal of minerals and materials characterization and engineering 1, no. 01 (2013): 24-28.
https://doi.org/10.4236/jmmce.2013.11005
Bedolla-Jacuinde, A., F. V. Guerra, A. J. Guerrero-Pastran, M. A. Sierra-Cetina, and S. Valdez-Medina. "Microstructural effect and wear performance of high chromium white cast iron modified with high boron contents." Wear 476 (2021): 203675.
https://doi.org/10.1016/j.wear.2021.203675
Bedolla-Jacuinde, Arnoldo, Francisco Guerra, Ignacio Mejia, and Uzzi Vera. "Niobium additions to a 15% Cr-3% C white iron and its effects on the microstructure and on abrasive wear behavior." Metals 9, no. 12 (2019): 1321.
https://doi.org/10.3390/met9121321
Chabak, Yuliia, Ivan Petryshynets, Vasily Efremenko, Michail Golinskyi, Kazumichi Shimizu, Vadym Zurnadzhy, Ivan Sili, Hossam Halfa, Bohdan Efremenko, and Viktor Puchy. "Investigations of Abrasive Wear Behaviour of Hybrid High-Boron Multi-Component Alloys: Effect of Boron and Carbon Contents by the Factorial Design Method." Materials 16, no. 6 (2023): 2530.
https://doi.org/10.3390/ma16062530
Chen, Xiang-Ru, Qi-Jie Zhai, Han Dong, Bao-Hua Dai, and Hardy Mohrbacher. "Molybdenum alloying in cast iron and steel." Advances in Manufacturing 8 (2020): 3-14.
https://doi.org/10.1007/s40436-019-00282-1
Çöl, Mustafa, Funda Gül Koç, Hasan Öktem, and Durmuş Kır. "The role of boron content in high alloy white cast iron (Ni-Hard 4) on microstructure, mechanical properties and wear resistance." Wear 348 (2016): 158-165.
https://doi.org/10.1016/j.wear.2015.12.007
Filipovic, Mirjana, Zeljko Kamberovic, and Marija Korac. "Solidification of Fe19Cr2. 9C2V alloy." Journal of Mining and Metallurgy, Section B: Metallurgy 50, no. 1 (2014): 27-30.
https://doi.org/10.2298/JMMB130314041F
Filipovic, Mirjana, Zeljko Kamberovic, and Marija Korac. "Solidification of high chromium white cast iron alloyed with vanadium." Materials transactions 52, no. 3 (2011): 386-390.
https://doi.org/10.2320/matertrans.M2010059
Guerra, Francisco Vapeani, Arnoldo Bedolla-Jacuinde, Jorge Zuno-Silva, Ignacio Mejia, Edgar Cardoso-Legorreta, and Alberto Arenas-Flores. "Effect of the simultaneous Ti and W addition on the microstructure and wear behavior of a high chromium white cast iron." Metallurgical Research & Technology 116, no. 6 (2019): 602.
https://doi.org/10.1051/metal/2019031
Li, Qian, Ya Long Zhang, Liang Zhang, Qian Wang, Zhuo Zhao, Dong Xu Chen, Hui Jin, Yi Yong Wang, and Jun Wei Zhang. "Effect of boron on the microstructural evolution and wear resistance of high-hardness Fe-based alloy coatings prepared by laser cladding." Surface and Coatings Technology 458 (2023): 129342.
https://doi.org/10.1016/j.surfcoat.2023.129342
Maratray, F., and R. Usseglio-Nanot. "FACTORS AFFECTING THE STRUCTURE OF CHROMIUM AND CHROMIUM--MOLYBDENUM WHITE IRONS." (1970).
Sudhakar, A. N., R. Markandeya, Kumar Pandey Ajoy, and D. Kaushik. "Effect of alloying elements on the microstructure and mechanical properties of high chromium white cast iron and Ni-Hard iron." Materials Today: Proceedings 61 (2022): 1006-1014.
https://doi.org/10.1016/j.matpr.2021.10.284
Wang, Shuai, Yingmin Li, Juan Wang, Tiegang Luo, Kaihong Zheng, Zhibin Zheng, Jun Long, and Yingfei Lin. "Study on the microstructure and properties of iron-based composites locally reinforced by in-situ submicron TiC particles." Materials Chemistry and Physics 287 (2022): 126376.
Downloads
Published
Issue
Section
License
Copyright (c) 2023 Marija Mihailović, Aleksandra Patarić, Branka Jordović
This work is licensed under a Creative Commons Attribution 4.0 International License.