A Circular Economy Approach to Convert Waste Dairy Scum Oil into Biodiesel for the Development of Sustainable Environment

Authors

  • Luqman Razzaq Department of Mechanical, Mechatronics and Manufacturing Engineering (New Campus), University of Engineering and Technology, Lahore 54000, Pakistan https://orcid.org/0000-0002-1229-0629

DOI:

https://doi.org/10.30544/MMD24

Abstract

The present study is an effort to examine a technique for evaluating the expenses associated with the production of biodiesel from waste dairy scum oil in Pakistan, to create an economic assessment of this option. A survey was conducted on ten dairies in Gujrat to encourage them participation in the biodiesel supply chain. The survey aimed to collect data on waste dairy scum creation, disposal methods and quantity, as well as purchase cost. The waste dairy scum oil was extracted by solvent extraction method. Acetone solvent has been used to extract the waste dairy scum oil. A two-step acid treatment was done to reduce the FFA value of WDSO from 4.6 to 0.98 mg KOH/g. The independent variables of the transesterification process parameters including catalyst concentration, methanol to oil ratio, temperature, speed, and reaction time were kept 0.25 w/w, 8.50:1, 57.50℃, 600 rpm, and 1h respectively. The maximum biodiesel yield at these operating parameters was observed 93%. The economic feasibility of the conversion of WDSO into biodiesel was assessed using the information obtained from the surveys conducted by the different dairy’s owners. Approximately 70% of diaries produced scum and wanted to convert this waste dairy scum into biodiesel. The net biodiesel production cost was found to be 171 rupees. The logistic cost of biodiesel produced from the WDSO was found to be 22 rupees. The overall cost of 1L biodiesel would be 193 rupees. A two-way sensitivity analysis was performed to determine the profit of the conversion of the WDSO into biodiesel. The environmental analysis revealed that the emissions like CO, HC, and NOx significantly reduced during the combustion of biodiesel as compared to conventional diesel.

Keywords:

Biodiesel, Circular Economy, Dairy scum oil, Transesterification

References

Abreu-Jaureguí, C, H E Reynel-Ávila, and A Bonilla-Petriciolet. 2023. "Biodiesel Production from Wastewater Scum of Dairy Industry: Lipid Extraction Studies and Reaction Routes." Fuel 342: 127868.

https://doi.org/10.1016/j.fuel.2023.127868

Adesra, Ankita, Vijay Kumar Srivastava, and Sunita Varjani. 2021. "Valorization of Dairy Wastes: Integrative Approaches for Value Added Products." Indian Journal of Microbiology 61 (3): 270-78.

https://doi.org/10.1007/s12088-021-00943-5

Afzal, Asif, Ümit Ağbulut, Manzoore Elahi M Soudagar, R K Abdul Razak, Abdulrajak Buradi, and C Ahamed Saleel. 2021. "Blends of Scum Oil Methyl Ester, Alcohols, Silver Nanoparticles and the Operating Conditions Affecting the Diesel Engine Performance and Emission: An Optimization Study Using Dragon Fly Algorithm." Applied Nanoscience 11: 2415-32.

https://doi.org/10.1007/s13204-021-02046-5

Ahmad, Umar Suffian, Muhammad Usman, Saddam Hussain, Atif Jahanger, and Maira Abrar. 2022. "Determinants of Renewable Energy Sources in Pakistan: An Overview." Environmental Science and Pollution Research 29 (19): 29183-201.

https://doi.org/10.1007/s11356-022-18502-w

Asghar, Rafiq, Mohd H Sulaiman, Zuriani Mustaffa, Nasim Ullah, and Waqas Hassan. 2023. "The Important Contribution of Renewable Energy Technologies in Overcoming Pakistan's Energy Crisis: Present Challenges and Potential Opportunities." Energy & Environment 34 (8): 3450-94.

https://doi.org/10.1177/0958305X221134110

Athar, Moina, and Sadaf Zaidi. 2020. "A Review of the Feedstocks, Catalysts, and Intensification Techniques for Sustainable Biodiesel Production." Journal of Environmental Chemical Engineering 8 (6): 104523.

https://doi.org/10.1016/j.jece.2020.104523

Balasubramanian, R, Anirbid Sircar, P Sivakumar, and K Anbarasu. 2018. "Production of Biodiesel from Dairy Wastewater Sludge: A Laboratory and Pilot Scale Study." Egyptian Journal of Petroleum 27 (4): 939-43.

https://doi.org/10.1016/j.ejpe.2018.02.002

Baskar, G, G Kalavathy, R Aiswarya, and I Abarnaebenezer Selvakumari. 2019. "Advances in Bio-Oil Extraction from Nonedible Oil Seeds and Algal Biomass." In Advances in Eco-Fuels for a Sustainable Environment, 187-210. Elsevier.

https://doi.org/10.1016/B978-0-08-102728-8.00007-3

Burchart-Korol, Dorota, Magdalena Gazda-Grzywacz, and Katarzyna Zarębska. 2020. "Research and Prospects for the Development of Alternative Fuels in the Transport Sector in Poland: A Review." Energies 13 (11): 2988.

https://doi.org/10.3390/en13112988

Castillo, Nahum Andrés Medellín, Bladir Salomón Rangel Nava, Alejandro Rocha Uribe, Miguel Mauricio Aguilera Flores, and Verónica Ávila Vázquez. 2021. "Producción Sustentable de Biodiesel Empleando Grasas Residuales de La Industria Láctea." Quimica Hoy 10 (4): 17-22.

https://doi.org/10.29105/qh10.4-268

Chandio, Abbas Ali, Abdul Rehman, Yuansheng Jiang, and Sanaullah Noonari. 2017. "Importance of the Dairy Industry and Economic Growth in Pakistan: An Empirical Study." Journal of Applied Environmental and Biological Sciences 7 (4): 20-31.

Choudhary, Monika, Sunanda Joshi, Vartika, Lavisha Rao, and Nidhi Srivastava. 2021. "Production of Biofuel from Disposed Food and Dairy Waste." Bioprospecting of Enzymes in Industry, Healthcare and Sustainable Environment, 123-38.

https://doi.org/10.1007/978-981-33-4195-1_6

Durham, R J, and J A Hourigan. 2007. "Waste Management and Co-Product Recovery in Dairy Processing." In Handbook of Waste Management and Co-Product Recovery in Food Processing, 332-87. Elsevier.

https://doi.org/10.1533/9781845692520.4.332

Etim, Anietie O, Paul Musonge, and Andrew C Eloka‐Eboka. 2020. "Effectiveness of Biogenic Waste‐derived Heterogeneous Catalysts and Feedstock Hybridization Techniques in Biodiesel Production." Biofuels, Bioproducts and Biorefining 14 (3): 620-49.

https://doi.org/10.1002/bbb.2094

Fawzy, Samer, Ahmed I Osman, John Doran, and David W Rooney. 2020. "Strategies for Mitigation of Climate Change: A Review." Environmental Chemistry Letters 18: 2069-94.

https://doi.org/10.1007/s10311-020-01059-w

Fayaz, H, M A Mujtaba, Manzoore Elahi M Soudagar, L Razzaq, Saad Nawaz, Muhammad Ahsan Nawaz, M Farooq, Asif Afzal, Waqar Ahmed, and T M Yunus Khan. 2021. "Collective Effect of Ternary Nano Fuel Blends on the Diesel Engine Performance and Emissions Characteristics." Fuel 293: 120420.

https://doi.org/10.1016/j.fuel.2021.120420

Friedemann, A. 2021. "Life after Fossil Fuels." A Reality Check on Alternative Energy. Cham (Suiza): Springer-Lecture Notes in Energy.

https://doi.org/10.1007/978-3-030-70335-6

Hanumante, Neeraj C, Yogendra Shastri, and Andrew Hoadley. 2019. "Assessment of Circular Economy for Global Sustainability Using an Integrated Model." Resources, Conservation and Recycling 151: 104460.

https://doi.org/10.1016/j.resconrec.2019.104460

Kalair, Anam, Naeem Abas, Muhammad Shoaib Saleem, Ali Raza Kalair, and Nasrullah Khan. 2021. "Role of Energy Storage Systems in Energy Transition from Fossil Fuels to Renewables." Energy Storage 3 (1): e135.

https://doi.org/10.1002/est2.135

Karmee, Sanjib Kumar, Raffel Dharma Patria, and Carol Sze Ki Lin. 2015. "Techno-Economic Evaluation of Biodiesel Production from Waste Cooking Oil-a Case Study of Hong Kong." International Journal of Molecular Sciences 16 (3): 4362-71.

https://doi.org/10.3390/ijms16034362

Korhonen, Jouni, Antero Honkasalo, and Jyri Seppälä. 2018. "Circular Economy: The Concept and Its Limitations." Ecological Economics 143: 37-46.

https://doi.org/10.1016/j.ecolecon.2017.06.041

Kumar, S P Jeevan, Garlapati Vijay Kumar, Archana Dash, Peter Scholz, and Rintu Banerjee. 2017. "Sustainable Green Solvents and Techniques for Lipid Extraction from Microalgae: A Review." Algal Research 21: 138-47.

https://doi.org/10.1016/j.algal.2016.11.014

Malode, Shweta J, K Keerthi Prabhu, Ronald J Mascarenhas, Nagaraj P Shetti, and Tejraj M Aminabhavi. 2021. "Recent Advances and Viability in Biofuel Production." Energy Conversion and Management: X 10: 100070.

https://doi.org/10.1016/j.ecmx.2020.100070

Mohd Johari, Siti Aminah, Muhammad Ayoub, Abrar Inayat, Sami Ullah, Maliha Uroos, Salman Raza Naqvi, and Sarah Farukkh. 2022. "Utilization of Dairy Scum Waste as a Feedstock for Biodiesel Production via Different Heating Sources for Catalytic Transesterification." ChemBioEng Reviews 9 (6): 605-32.

https://doi.org/10.1002/cben.202200003

Mujtaba, M A, M A Kalam, H H Masjuki, M Gul, Manzoore Elahi M Soudagar, Hwai Chyuan Ong, Waqar Ahmed, A E Atabani, L Razzaq, and Mnam Yusoff. 2020. "Comparative Study of Nanoparticles and Alcoholic Fuel Additives-Biodiesel-Diesel Blend for Performance and Emission Improvements." Fuel 279: 118434.

https://doi.org/10.1016/j.fuel.2020.118434

Paraschiv, Spiru, and Lizica Simona Paraschiv. 2020. "Trends of Carbon Dioxide (CO2) Emissions from Fossil Fuels Combustion (Coal, Gas and Oil) in the EU Member States from 1960 to 2018." Energy Reports 6: 237-42.

https://doi.org/10.1016/j.egyr.2020.11.116

Razzaq, Luqman, Muhammad Mujtaba Abbas, Ahsan Waseem, Tahir Abbas Jauhar, H Fayaz, M A Kalam, Manzoor Elahi M Soudagar, A S Silitonga, and Usama Ishtiaq. 2023. "Influence of Varying Concentrations of TiO2 Nanoparticles and Engine Speed on the Performance and Emissions of Diesel Engine Operated on Waste Cooking Oil Biodiesel Blends Using Response Surface Methodology." Heliyon 9 (7).

https://doi.org/10.1016/j.heliyon.2023.e17758

Rosa, Ana Claudia Santos da, Natália Stevanato, Isabela Iwassa, Vitor Augusto dos Santos Garcia, and Camila da Silva. 2019. "Extração Assistida Por Ultrassom Do Óleo Das Sementes de Macaúba Utilizando Acetato de Etila Como Solvente." Brazilian Journal of Food Technology 22.

Sandaka, Bhanu Prakash, and Jitendra Kumar. 2023. "Alternative Vehicular Fuels for Environmental Decarbonization: A Critical Review of Challenges in Using Electricity, Hydrogen, and Biofuels as a Sustainable Vehicular Fuel." Chemical Engineering Journal Advances, 100442.

https://doi.org/10.1016/j.ceja.2022.100442

Sivakumar, P, K Anbarasu, and S Renganathan. 2011. "Bio-Diesel Production by Alkali Catalyzed Transesterification of Dairy Waste Scum." Fuel 90 (1): 147-51.

https://doi.org/10.1016/j.fuel.2010.08.024

Soudagar, Manzoore Elahi M, Haris Mahmood Khan, T M Yunus Khan, Luqman Razzaq, Tahir Asif, M A Mujtaba, Abrar Hussain, Muhammad Farooq, Waqar Ahmed, and Kiran Shahapurkar. 2021. "Experimental Analysis of Engine Performance and Exhaust Pollutant on a Single-Cylinder Diesel Engine Operated Using Moringa Oleifera Biodiesel." Applied Sciences 11 (15): 7071.

https://doi.org/10.3390/app11157071

Srikanth, H V, J Venkatesh, Sharanappa Godiganur, S Venkateswaran, and Bhaskar Manne. 2017. "Bio-Based Diluents Improve Cold Flow Properties of Dairy Washed Milk-Scum Biodiesel." Renewable Energy 111: 168-74.

https://doi.org/10.1016/j.renene.2017.03.092

Wang, Jiannan, and Waseem Azam. 2024. "Natural Resource Scarcity, Fossil Fuel Energy Consumption, and Total Greenhouse Gas Emissions in Top Emitting Countries." Geoscience Frontiers 15 (2): 101757.

https://doi.org/10.1016/j.gsf.2023.101757

Downloads

Published

27-03-2024

Issue

Section

Industry 4.0 in the circular economy and environmental protection and recovery