Alternative Reductants for the Blast Furnace Process and Catalytic Treatments of Exhaust Gases: a Review

Authors

  • Vesna Nikolić University of Belgrade, Innovation Center of the Faculty of Technology and Metallurgy https://orcid.org/0000-0003-3939-6092
  • Željko Kamberović University of Belgrade, Faculty for Technology and Metallurgy, Serbia https://orcid.org/0000-0003-0507-5346
  • Marija Štulović University of Belgrade, Innovation Center of the Faculty of Technology and Metallurgy
  • Dragana Radovanović University of Belgrade, Innovation Center of the Faculty of Technology and Metallurgy https://orcid.org/0000-0002-2935-7711

DOI:

https://doi.org/10.30544/MMD27

Abstract

Blast Furnace (BF) process is dominant in the iromaking industry in the World. Growing demand for steelmaking raw materials results in fast consumption of fossil fuels, which are required for the BF operation and also serve as reducing agents. To lower the carbon footprint and achieve sustainable development, as well as circular economy, there is an increased need for using alternative reducing agents for BFs, such as waste plastics, bio-based materials etc. Those materials can be recycled or upcycled by utilization in BF process. Catalytic recycling/upcycling of exhaust gases was proposed, as it could be highly profitable, and, as well lower the carbon footprint of the BF process.

Keywords:

Blast Furnace, Alternative reductants, Waste plastics recycling, Catalytic treatments, Carbon neutrality
Supporting Agencies
This work was supported by the Ministry of Science, Technological Development and Innovation of the Republic of Serbia (Contract No. 451-03-66/2024-03/200287)

References

Al-Fatesh, A. S., A. H. Fakeeha, A. A. Ibrahim, and A. E. Abasaeed. "Ni supported on La2O3+ZrO2 for dry reforming of methane: The impact of surface adsorbed oxygen species." International Journal of Hydrogen Energy 46, no. 5 (2021): 3780-3788.

https://doi.org/10.1016/j.ijhydene.2020.10.164

Al-Moftah, A. M. S. H., R. Marsh, and J. Steer. "Thermal Decomposition Kinetic Study of Non-Recyclable Paper and Plastic Waste by Thermogravimetric Analysis." ChemEngineering 5, no. 3 (2021): 54-70.

https://doi.org/10.3390/chemengineering5030054

Bazaluk, Oleg, Lina Kieush, Andrii Koveria, Johannes Schenk, Andreas Pfeiffer, Heng Zheng, Vasyl Lozynskyi, et al. "Metallurgical Coke Production with Biomass Additives: Study of Biocoke Properties for Blast Furnace and Submerged Arc Furnace Purposes." Materials 15 (2022): 1147.

https://doi.org/10.3390/ma15031147

Daniel J. C. Stewart, Lucy V. Fisher, Michael E. A. Warwick, David Thomson, and Andrew R. Barron. "Facemasks and ferrous metallurgy: improving gasification reactivity of low‑volatile coals using waste COVID‑19 facemasks for ironmaking application." Scientific Reports 12 (2022): 2693.

https://doi.org/10.1038/s41598-022-06691-w

Deng, L., and T. A. Adams. "Techno-economic analysis of coke oven gas and blast furnace gas to methanol process with carbon dioxide capture and utilization." Energy Conversion and Management 204 (2020): 112315.

https://doi.org/10.1016/j.enconman.2019.112315

Fazlikeshteli, S., X. Vendrell, and J. Llorca. "Low-temperature partial oxidation of methane over Pd-Ni bimetallic catalysts supported on CeO2." International Journal of Hydrogen Energy 48, no. 32 (2023): 12024-12035.

https://doi.org/10.1016/j.ijhydene.2022.07.020

Ghanbari, H., F. Pettersson, and H. Saxén. "Sustainable development of primary steelmaking under novel blast furnace operation and injection of different reducing agents." Chemical Engineering Science 129 (2015): 208-222.

https://doi.org/10.1016/j.ces.2015.01.069

Jiang, G., D. A. Sanchez Monsalve, P. Clough, Z. Jiang, and G. A. Leeke. "Understanding the Dechlorination of Chlorinated Hydrocarbons in the Pyrolysis of Mixed Plastics." ASC Sustainable Chemistry and Engineering 9 (2021): 1576-1589.

https://doi.org/10.1021/acssuschemeng.0c06461

Jing, Y., Y. Wang, S. Furukawa, J. Xia, C. Sun, M. J. Hülsey, H. Wang, Y. Guo, Dr. X. Liu, and N. Yan. "Towards the Circular Economy: Converting Aromatic Plastic Waste Back to Arenes over a Ru/Nb2O5 Catalyst." Angewandte Chemie International Edition 60, no. 10 (2021): 5527-5535.

https://doi.org/10.1002/anie.202011063

Kamberović, Ž., A. Vučinić, E. Janković, M. Gavrilovski, Z. Anđić, and M. Korać. "Stokholmska konvencija o dugotrjnim organskim zagađujućim supstancama - Uputstvo o najboljim dostupnim tehnikama i najboljim praksama po životnu sredinu koje se odnose na Član 5 i Aneks C." Savez inženjera metalurgije Srbije, 2011.

Kim, H., B. Kim, W. Jang, J. Shim, K. Jeon, H. Na, Y. Lee, B. Jeon, and H. Roh. "Effect of support materials and Ni loading on catalytic performance for carbon dioxide reforming of coke oven gas." International Journal of Hydrogen Energy 44, no. 16 (2019): 8233-8242.

https://doi.org/10.1016/j.ijhydene.2019.01.269

Mazhandu, Z. S. M., E. Muzenda, M. Belaid, T. A. Mamvura, and T. Nhubu. "Plastic waste use in the blast furnace as a reducing agent.", https://hdl.handle.net/10210/458868

Morita, Y., Y. Saito, S. Kumagai, T. Kameda, T. Shiratori, and T. Yoshioka. "Fluorine recovery through alkaline defluorination of polyvinylidene fluoride." Journal of Material Cycles and Waste Management 26 (2024): 669-678.

https://doi.org/10.1007/s10163-023-01749-x

Nikolić, V., J. Đokić, Ž. Kamberović, A. Marinković, S. Jevtić, and Z. Anđić. "Investigating possibilities for synthesis of novel sorbents and catalyst carriers based on ceramics with controlled open porosity." Hemijska Industrija (Chemical Industry) 76, no. 2 (2022): 87-95.

https://doi.org/10.2298/HEMIND210809005N

Nikolić, V. D., J. M. Đokić, D. P. Dinić, A. D. Marinković, S. O. Jevtić, Z. M. Anđić, and Ž. J. Kamberović. "Sinteza inovativnih keramičkih sorbenata i nosača katalizatora hijerarhijske poroznosti (Synthesis of innovative ceramic sorbents and catalyst supports with hierarchical porosity)." Tehnika - novi materijali 32, no. 3 (2023): 269-273.

https://doi.org/10.5937/tehnika2303269K

Ou, Z., Z. Zhang, C. Qin, H. Xia, T. Deng, J. Niu, J. Ran, and C. Wu. "Highly active and stable Ni/perovskite catalysts in steam methane reforming for hydrogen production." Sustainable Energy Fuels 5 (2021): 1845-1856.

https://doi.org/10.1039/D1SE00082A

Roy, Subhnit K., Deepak Nayak, and Swagat S. Rath. "A review on the enrichment of iron values of low-grade Iron ore resources using reduction roasting-magnetic separation." Powder Technology 367 (2020): 796-808.

https://doi.org/10.1016/j.powtec.2020.04.047

Tang, H., Y. Sun, T. Rong, and Zhancheng Guo. "Reaction model and reaction behavior of carbon composite briquette in blast furnace." Powder Technology 377 (2021): 832-842.

https://doi.org/10.1016/j.powtec.2020.09.034

Trinkel, V., N. Kieberger, T. Bürgler, H. Rechberger, and J. Fellner. "Influence of waste plastic utilisation in blast furnace on heavy metal emissions." Journal of Cleaner Production 94 (2015): 312-320.

https://doi.org/10.1016/j.jclepro.2015.02.018

Zhang, S., K. Zou, B. Li, H. Shim, and Y. Huang. "Key Considerations on The Industrial Application of Lignocellulosic Biomass Pyrolysis toward Carbon Neutrality." Engineering 29 (2023): 35-38.

https://doi.org/10.1016/j.eng.2023.02.015

Zhao, X., M. Korey, K. Li, K. Copenhaver, H. Tekinalp, S. Celik, K. Kalaitzidou, R. Ruan, and S. Ozcan. "Plastic waste upcycling toward a circular economy." Chemical Engineering Journal 428 (2022): 131928.

https://doi.org/10.1016/j.cej.2021.131928

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Published

27-03-2024

Issue

Section

Industry 4.0 in the circular economy and environmental protection and recovery