Quantitative Analysis of Mechanically Alloyed CuZrB Powders
DOI:
https://doi.org/10.30544/MMD44Abstract
Copper matrix composites are proving to be a suitable match for the present engineering needs of the market where higher temperature resistance and good microstructural stability are required. Powder metallurgy technique was used to procure the powder mixture, Cu-2Zr-0.6B (wt.%). Different mechanical alloying (MA) parameters were examined with the main focus on time, ranging from 10 h to 40 h. SEM analysis was employed to determine structural and morphological changes of the mechanically alloyed powder mixture. MIPAR image analysis software was used to complete the quantitative analysis of the mechanically alloyed CuZrB powders. Changes in size and shape of powder particles were determined during up to 40 h of MA with key points after every 10 h. It was concluded that the powder particle size decreases as the MA time increases. With the increase in MA time the area of each particle decreases due to the dominant plastic deformation mechanisms as particles undergo high forces through ball-particle-ball and wall-particle-ball collisions during the MA process.
Keywords:
Cu matrix composites, powder metallurgy, mechanical alloying, MiparReferences
Akhtar, S., Saad, M., Misbah, R., & Sati, M. C. (2018). Recent Advancements in Powder Metallurgy: A Review. Materials Today: Proceedings (Vol. 5). 2214-7853
Alkindi, Y., Alshammari, Y., Yang, F., & Bolzoni, L. (2023). Joint effect of Zr and Cu on the properties of new powder metallurgy Ti–Zr–Cu alloys. Materials Science and Engineering: A, 867, 144708. https://doi.org/10.1016/J.MSEA.2023.144708
Bansal S. A., E., Khanna, V., Gupta, P. (2023). Metal Matrix Composites; Fabrication, Production, and 3D Printing, CRC Press.
Cai, Y., Su, Y., Liu, K., Hua, A., Wang, X., Cao, H., Zhang, D., & Ouyang, Q. (2023). Effect of Sc microalloying on fabrication, microstructure and mechanical properties of SiCp/Al–Cu–Mg-Sc composites via powder metallurgy. Materials Science and Engineering: A, 877. https://doi.org/10.1016/j.msea.2023.145152
Chawla, N., & Chawla, K. K. (n.d.). (2016), Metal Matrix Composites, Springer Science & Business Media.
Eessaa, A. K., Elkady, O. A., & El-Shamy, A. M. (2023). Powder metallurgy as a perfect technique for preparation of Cu–TiO2 composite by identifying their microstructure and optical properties. Scientific Reports, 13(1). https://doi.org/10.1038/s41598-023-33999-y
El-Eskandarany, M. Sherif. (2001). Mechanical alloying for fabrication of advanced engineering materials. Noyes Publications.
Gautam, Y. K., Somani, N., Kumar, M., & Sharma, S. K. (2018). A review on fabrication and characterization of copper metal matrix composite (CMMC). AIP Conference Proceedings, https://doi.org/10.1063/1.5058254
Jamwal, A., Mittal, P., Agrawal, R., Gupta, S., Kumar, D., Sadasivuni, K. K., & Gupta, P. (2020). Towards sustainable copper matrix composites: Manufacturing routes with structural, mechanical, electrical and corrosion behaviour. Journal of Composite Materials 54(19), 2635–2649. SAGE Publications Ltd. https://doi.org/10.1177/0021998319900655
Malaki, M. (2021). An Insight into Metal Matrix Composites with Nano Size Reinforcement. Encyclopedia of Materials: Composites, 1, 42–51. Elsevier. https://doi.org/10.1016/B978-0-12-803581-8.11798-9
Paul, M., Alshammari, Y., Yang, F., & Bolzoni, L. (2023). Processing and properties of powder metallurgy Ti-Cu-Nb alloys. Journal of Alloys and Compounds, 944, 169041. https://doi.org/10.1016/J.JALLCOM.2023.169041
Pingale, A. D., Owhal, A., Katarkar, A. S., Belgamwar, S. U., & Rathore, J. S. (2021). Recent researches on Cu-Ni alloy matrix composites through electrodeposition and powder metallurgy methods: A review. Materials Today: Proceedings, 47, 3301–3308. https://doi.org/10.1016/j.matpr.2021.07.145
Prasad Yadav, T., Manohar Yadav, R., & Pratap Singh, D. (2012). Mechanical Milling: a Top Down Approach for the Synthesis of Nanomaterials and Nanocomposites. Nanoscience and Nanotechnology, 2(3), 22–48. https://doi.org/10.5923/j.nn.20120203.01
Ružić, J., Stašić, J., Rajković, V., & Božić, D. (2014). Synthesis, microstructure and mechanical properties of ZrB2 nano and microparticle reinforced copper matrix composite by in situ processings. Materials and Design, 62, 409–415. https://doi.org/10.1016/j.matdes.2014.05.036
Şap, S., Uzun, M., Usca, Ü. A., Pimenov, D. Y., Giasin, K., & Wojciechowski, S. (2021). Investigation on microstructure, mechanical, and tribological performance of Cu base hybrid composite materials. Journal of Materials Research and Technology, 15, 6990–7003. https://doi.org/10.1016/J.JMRT.2021.11.114
Shaik, M. A., & Golla, B. R. (2019). Development of highly wear resistant Cu - Al alloys processed via powder metallurgy. Tribology International, 136, 127–139. https://doi.org/10.1016/j.triboint.2019.03.055
Shaik, M. A., Golla, B. R., & Khaple, S. (2021). Effect of powder processing and alloying additions (Al/ZrB2) on the microstructure, mechanical and electrical properties of Cu. Advanced Powder Technology, 32(9), 3314–3323. https://doi.org/10.1016/j.apt.2021.07.012
Shang, W., Wang, H., Zhao, S., Zhao, X., Xu, H., Lu, H., Chen, D., Fan, B., & Zhang, R. (2014). Processing and properties of ZrB2-Cu composites sintered by hot-pressing sintering. Key Engineering Materials, 602–603, 447–450. https://doi.org/10.4028/www.scientific.net/KEM.602-603.447
Sosa J., Huber D., Welk B., Fraser H. (2014). Development and application of MIPAR™: a novel software package for two- and three-dimensional microstructural characterization, Integrating Materials and Manufacturing Innovation, 3(1), 123-140, https://doi.org/10.1186/2193-9772-3-10
Srivatsan, T. S., Pradeep, Rohatgi, K., Murph, S. H. (2022) Metal-Matrix Composites Advances in Processing, Characterization, Performance and Analysis, Springer Nature
Suryanarayana, C. (2007). Mechanical alloying and milling.
Taha, M. A., Youness, R. A., & Zawrah, M. F. (2019). Review on nanocomposites fabricated by mechanical alloying. International Journal of Minerals, Metallurgy and Materials 26(9), 1047–1058. https://doi.org/10.1007/s12613-019-1827-4
Wang, Z., Tan, Y., & Li, N. (2023). Powder Metallurgy of Titanium Alloys: A Brief Review. Journal of Alloys and Compounds, 171030. https://doi.org/10.1016/j.jallcom.2023.171030
Wong-Ángel, W. D., Téllez-Jurado, L., Chávez-Alcalá, J. F., Chavira-Martínez, E., & Verduzco-Cedeño, V. F. (2014). Effect of copper on the mechanical properties of alloys formed by powder metallurgy. Materials & Design, 58, 12–18. https://doi.org/10.1016/J.MATDES.2014.02.002
Wu, Z., Hu, J., Xin, Z., Qin, L., Jia, Y., & Jiang, Y. (2023). Microstructure and properties of Cu-Zn-Cr-Zr alloy treated by multistage thermo-mechanical treatment. Materials Science and Engineering: A, 870. https://doi.org/10.1016/j.msea.2023.144679
Zhang, Z., Sheng, Y., Xu, X., & Li, W. (2015). Microstructural Features and Mechanical Properties of in Situ Formed ZrB2/Cu Composites. Advanced Engineering Materials, 17(9), 1338–1343. https://doi.org/10.1002/adem.201400532
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