Stability of Solid Residue After Integral Treatment of Acid Mine Drainage

Authors

  • Nela Petronijević Institute for Technology of Nuclear and Other Mineral Raw Materials, Belgrade, Republic of Serbia
  • Dragana Radovanović Innovation Center of the Faculty of Technology and Metallurgy in Belgrade, University of Belgrade, Belgrade, Serbia https://orcid.org/0000-0002-2935-7711
  • Srđan Stanković Federal Institute for Geosciences and Natural Resources, Hannover, Germany
  • Miroslav Sokić Institute for technology of nuclear and other mineral raw materials, Belgrade, Serbia https://orcid.org/0000-0002-4468-9503
  • Željko Kamberović Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia
  • Antonije Onjia Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia https://orcid.org/0000-0002-5694-7960
  • Gvozden Jovanović Institute for technology of nuclear and other mineral raw materials, Belgrade, Serbia https://orcid.org/0000-0002-9754-2230

DOI:

https://doi.org/10.30544/MMD6

Abstract

Acid mine drainage poses a significant environmental challenge resulting from mining activities. It can occur during and after the exposure of sulfide minerals to water, oxygen, or oxidizing bacteria. Extensive copper ore exploitation, processing, and the deposition of substantial amounts of mining waste have caused severe geological, hydrogeological, and geomorphological changes, including soil contamination, as well as local or even regional-scale pollution of rivers and groundwater. This study focuses on the utilization of waste mine waters and unbalanced portions of the mine deposit, such as flotation tailings, to transform their negative characteristics into environmentally friendly ones. In previous research by the authors, acid mine water from Robule, a part of the Bor copper mining and smelting complex in Serbia, was effectively treated using flotation tailings, resulting in a solution suitable for safe discharge. This paper investigates the characteristics of the solid residue remaining after the treatment of modified flotation tailings to assess the feasibility of its safe disposal back into the environment. Standard procedures such as TCLP and EN 12457-4 tests were employed to evaluate the leaching characteristics of the solid residue. Additionally, the residue underwent long-term leaching with melted snow to simulate environmental conditions over one year, and the drainage water was analyzed and compared with the results of the standard leaching procedures. The investigated treatments demonstrate improved economic and environmental outcomes, with a process tailored to environmental preservation.

Keywords:

acidic mine drainage, flotation tailings, circular economy, fly ash
Supporting Agencies
This research was supported by the Ministry of Science, Technological Developments and Innovation of the Republic of Serbia (Contract number: 451-03-47/2023-01/200023; 451-03-47/2023-01/200135).

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Published

30-06-2023

Issue

Section

Hydrometallurgy: Extraction, Recovery, and Environment